How knowing about MF of HazChem helps?
Material Factor (MF)
of Hazardous chemicals
Definition: Material Factor is a measure of the
energy potential of the most hazardous material, or mixture of material,
present. MF denoted by a numerical from 0 to 40, with 40 being the highest and
0 the lowest energy containing materials. The degree of hazards associated with
the material also indicated by the number in increasing order from 0 to 40.
Importance of Material Factor (MF): The direct (fire heat burn) or
indirect (fire caused smoke or reaction product) injury or health hazards
arising from any chemical is decided prominently by three characteristic
factors, e.g. flammability, reactivity, and toxicity. Therefore, understanding of MF - as function
of these factors, by all those who are associated with handling (storing,
dispensing, shifting, processing, using, transporting, pumping, loading,
unloading, and disposing) is important in order to take necessary control
measures to avoid explosion, fire, and/or hazardous reaction products because
of single or mixture of chemical. The degree of prevention, protection and
containment efforts in handling a particular chemical or mixture of chemicals
may be adopted based on the numerical value of Material Factor (MF).
Determination of the Material Factor
(MF): It is
determined using only two properties of materials a) Flammability and b)
reactivity. Flammability where depends upon the flash point of the chemical,
reactivity characterised by instability and water reactivity of a chemical. The
above table may be used to derive Material
Factor (MF) if any of the four characteristics associated with that particular
chemicals area known:
·
Flash
Point (0C)
·
Hcv
Value (kJ.bar/mol) – it is estimated by multiplying heat of combustion
(kJ/mol) and vapour pressure at 300 0K (bar)
·
Adiabatic
decomposition temperature, Td (0K)
·
Any
two components of NFPA Hazards figure(Flammability Nf, Reactivity Nr,
Toxicity Nt)
For any query related to this may be logged at feedback window at www.safetitude.com
Comments
Post a Comment